MATERIAL SAFETY DATA SHEET
PRODUCT: ä -3-CARENE
1. IDENTIFICATION OF SUBSTANCE AND OF THE COMPANY.
1.1 Identification of the substance.
1.2 Use of the substance.
This material is only used as an ingredient in the manufacturing of aromatic bases.
1.3 Company identification:
SUPERMINT EXPORTS (P) LTD.
Panwaria, 4 th Km Bareilly Road,
Rampur-244901, U.P., INDIA
Telephone : (00) 91 595 235 7332 Fax : (00) 91 595 235 7333
1.4 Emergency Telephone: +91 595 235 7332
Timetable : Monday to Saturday: 10.00 AM to 05.00 PM (IST)
2. HAZARD IDENTIFICATION
2.1 Human hazardous : In his pure state, and when it is not correctly manipulated or when
inhaled. Excessively, product can cause irritation of the skin, eyes and respiratory tracks.
2.2 Environment hazardous : if liked, product can pollute subsoil, soil and superficial water.
3. COMPOSITION / INFORMATION ON INGREDIENTS
3.1 CHEMICAL INFORMATION: 3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
3.2 Nº CAS: 13466-78-9
3.3 Nº EINECS: 236-719-3
3.4 FEMA: 3821
3.5 Nº CEE: --
3.6 MOLECULAR FORMULA: C10 H16
3.7 MOLECULAR WEIGHT: 136
4. FIRST AID MEASURES.
Inhalation In case of excessive inhalation, expose the person to fresh air and if
Necessary, obtain medical assistance.
Symptoms: Choking, drowsiness, respiratory disruptions
Eye contacts immediately rinse eyes with water. If any sign of tissue damage or
Persistent irritation is apparent, obtain medical assistance immediately.
Symptoms: irritation, reddening.
Skin contact Remove contaminated clothing. Wash skin immediately with water and
Soap. If any sign of tissue damage or persistent irritation is apparent
Obtain medical assistance immediately.
Symptoms: irritation, stinging.
Ingestion Rinse mouth with water. Obtain medical assistance immediately. Do not
Symptoms: queasiness, stomach aches.
5. FIRE-FIGHTING MEASURES.
Ways of extinction : CO2, extinction powder or foam.
Do not use: water directly.
Individual protection equipments : use general extinction equipments for fire fighting and
use breathing equipment. Avoid inhalation of fumes
Dangers : Do not allow that the spilling of the fire extinction of fire
flows into drain or water.
High temperatures can provoke high pressures inside
the closed packages. O not breathes fumes or vapours.
6. ACCIDENTAL RELEASE MEASURES.
6.1. Personal precautions:
Remove all sources of ignition.
In case of existing, avoid breathing combustion vapours.
Provide proper ventilation. Avoid breathing vapours.
Avoid the contact with the skin, eyes and mucous.
See sections 8 and 13.
6.2. Environmental precautions:
Spillages should be contained by use of sand or another inert material.
Avoid penetration in the sewage system and surface water.
6.3. Methods for cleaning:
Spillages should be contained by use of sand or another inert material. All the materials used
for cleaning spillages should be disposed of promptly in accordance with current legislation.
7. EXPOSURE CONTROLS/ PERSONAL PROTECTION.
7.1. Exposure limit values
Exposure limit biological :
7.2. Exposure controls :
7.2.1. Occupational exposure controls
18.104.22.168. Respiratory protection: Avoid breathing directly on the product. Apply
local ventilation when appropriate.
22.214.171.124. Hand protection: Use chemical resistant gloves
126.96.36.199. Eye protection: Use safety glasses
188.8.131.52. Skin protection: Avoid skin contact
7.2.2. Environment exposure control: Avoid discharging into drainage water. Only
eliminate by authorized companies.
8. PHYSICAL AND CHEMICAL PROPERTIES.
8.1 General information:
Colour: COLOURLESS-PALE YELLOW
8.2 Important health, safety and environment information:
Boiling point/Boiling range: 169-174ºC
Flash point: 45ºC
Relative density: 0,86 - 0,865
Partion coeff. (n-octanol/water) :
8.3 Other information:
9. STABILITY AND REACTIVITY.
Stable under normal conditions
9.1 Conditions to avoid: High temperatures, pressure and inadequate manipulation of
9.2 Materials to avoid: Acid, alkaline and oxidizing agents
9.3 Hazardous decomposition products: Under normal conditions of storage are not
Known dangerous substances in decomposition..
10. TOXICOLOGICAL INFORMATION.
Toxic kinetics, metabolism and distribution:
Acute effects (acute toxicity, irritation and corrosively):
Repeated dose toxicity: Due to the lack of adequate toxicology studies, the product has to
be considered as possible health hazard, and therefore it is supposed to manipulate it safety
with all possible kinds of protection.
CMR Effects(carcinogenity, mutagenicity and toxicity for reproduction):
11. ECOLOGICAL INFORMATION.
11.3 PERSISTENCE AND DEGRADABILITY:
11.4 BIOACCUMULATIVE POTENTIAL:
11.5 RESULTS OF PBT ASSESSMENT:
11.6 OTHER ADVERSE EFFECTS:
12. DISPOSAL CONSIDERATIONS.
Respect the local or national norms about elimination of residues and packages appropriate
elimination method : whenever possible, it is better to recycle than deposing or incinerating.